Nano-sized sensors that detect volatile organic compounds-harmful pollutants released from paints, cleaners, pesticides and other products
A team of researchers from the National Institute of Standards and Technology (NIST), George Mason University and the University of Maryland has made nano-sized sensors that detect volatile organic compounds—harmful pollutants released from paints, cleaners, pesticides and other products—that offer several advantages over today's commercial gas sensors, including low-power room-temperature operation and the ability to detect one or several compounds over a wide range of concentrations.
The recently published work* is proof of concept for a gas sensor made of a single nanowire and metal oxide nanoclusters chosen to react to a specific organic compound. This work is the most recent of several efforts at NIST that take advantage of the unique properties of nanowires and metal oxide elements for sensing dangerous substances.
Modern commercial gas sensors are made of thin, conductive films of metal oxides. When a volatile organic compound like benzene interacts with titanium dioxide, for example, a reaction alters the current running through the film, triggering an alarm. While thin-film sensors are effective, many must operate at temperatures of 200° C (392° F) or higher. Frequent heating can degrade the materials that make up the films and contacts, causing reliability problems. In addition, most thin-film sensors work within a narrow range: one might catch a small amount of toluene in the air, but fail to sniff out a massive release of the gas. The range of the new nanowire sensors runs from just 50 parts per billion up to 1 part per 100, or 1 percent of the air in a room.
Further, each nanowire is a defect-free single crystal, rather than the conglomeration of crystal grains in thin-film sensors, so they're less prone to degradation. In reliability tests over the last year, the nano-sized sensors have not experienced failures. While the team's current experimental sensors are tuned to detect benzene as well as the similar volatile organic compounds toluene, ethylbenzene and xylene, their goal is to build a device that includes an array of nanowires and various metal oxide nanoclusters for analyzing mixtures of compounds. They plan to collaborate with other NIST teams to combine their ultraviolet light approach with heat-induced nanowire sensing technologies.
The portion of this work conducted at George Mason University was funded by the National Science Foundation.
* G.S. Aluri, A. Motayed, A.V. Davydov, V.P. Oleshko, K.A. Bertness, N.A. Sanford and M.V. Rao. Highly selective GaN-nanowire/TiO2-nanocluster hybrid sensors for detection of benzene and related environment pollutants. Nanotechnology. 22 295503 doi: 10.1088/0957-4484/22/29/295503
Contact: Michael Baum firstname.lastname@example.org 301-975-2763 National Institute of Standards and Technology (NIST)